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At this stage, the material availability check is only available for production orders that are job scheduled. There is not really a good reason why operations scheduled orders would require a different process. Please enable the functionality for the operations scheduled production orders.
STATUS DETAILS
Completed

Administrator on 4/18/2023 8:30:26 PM
Thank you for your feedback. We released this feature and it is named Material availability check for operations scheduled production orders in release 10.0.34.
Sincerely,
Johan Hoffmann
PM, Microsoft