The Microsoft Invoice Capture Apps can process a "Cost Type" of invoice where it can generate an invoice journal in accounts payable. The journal posts all the expense to the default expense account that is associated with the vendor.
There is is currently no ability to select another GL account (and dimension combination)
In addition expenses cannot be allocated to other legal entities especially in the case of larger organization with multiple legal entities or shared service scenarios.
Users would literally have to re-create all the necessary lines for the expense allocation to one or multiple legal entities in the journal.
A more robust invoice capture solution would allow users the ability to to allocate expense to more than one expense account (and dimensions) as well as more than one legal entity.